Effect of multiwalled carbon nanotubes on the properties of PMMA/PEO blends

Khalid Saeed, Nasib Khan

Research output: Contribution to journalArticlepeer-review

4 Citations (Scopus)

Abstract

Poly (methyl methacrylate) (PMMA)/Poly ethylene oxide (PEO) (15 wt.% PMMA/85 wt.% PEO (PMMA/PEO-A) and 30 wt.% PMMA/70 wt.% PEO (PMMA/PEO-B)) blends, and functionalized multiwalled carbon nanotubes (F-MWNTs) filled PMMA/PEO-A and PMMA/PEO-B composites were prepared via solution casting technique. The morphological study showed the formation of cracks in F-MWNTs/PMMA/PEO blend. The mechanical properties of PMMA/PEO blend were decreased by incorporation of F-MWNTs, which might be due to less compatibility between F-MWNTs and PMMA/PEO blends. Neat PEO upon crystallization showed distinct sized spherulites, which decreased by the incorporation of F-MWNTs (nucleation effect of FMWNTs). The X-ray diffraction (XRD) analyses revealed that the intensity of peaks decreased by incorporation of nanotubes, which means that the PEO crystallinity was suppressed in the presence of F-MWNTs. The thermal stabilities of PMMA/PEO blend were improved by incorporation of F-MWNTs.

Original languageEnglish
Pages (from-to)59-64
Number of pages6
JournalJournal of the Mexican Chemical Society
Volume58
Issue number1
Publication statusPublished - 2014
Externally publishedYes

Keywords

  • Composites
  • Multiwalled carbon nanotubes
  • Polymer blends
  • Spherulites

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