High-Performance Au Nanorods as SERS Substrates for Environmental Monitoring Facilitated by the Organizing Power of Nanocellulose from Agave Palm Leaves, a Bio-Waste

Hasna M. Abdul Hakkeem; Aswathy Babu; Saju Pillai

doi:10.1007/978-3-030-76081-6_82

High-Performance Au Nanorods as SERS Substrates for Environmental Monitoring Facilitated by the Organizing Power of Nanocellulose from Agave Palm Leaves, a Bio-Waste

Hasna M. Abdul Hakkeem
, Aswathy Babu
, Saju Pillai

National Institute for Interdisciplinary Science and Technology
Academy of Scientific and Innovative Research

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution › peer-review

1 Citation (Scopus)

Abstract

In search of a biocompatible and sustainable platform for surface-enhanced Raman scattering (SERS) studies, nanorods with a high aspect ratio of coinage metals such as gold, silver, and copper augment the peak intensity, but the shelf life of metal nanoparticles is questionable. Here, we report the synthetic strategy of parallelly aligned nanorods achieved by the synergetic action of carboxyl-functionalized nanocellulose fibers (TNCF) and cetyl trimethyl ammonium bromide (CTAB) as both reducing and capping agents. The synthesized parallel nanorods shows excellent SERS enhancement down to 10⁻⁷ M concentration of methylene blue and 0.1 ppm of thiram (pesticide). Additionally, TEMPO-oxidized nanocellulose fibers-supported nanorods colloid showed excellent shelf life. Our approach using TEMPO-oxidized nanocellulose fibers-supported Au nanorods can be considered an efficient and reproducible surface-enhanced Raman scattering substrate environmental monitoring.

Original language	English
Title of host publication	Sustainable Energy-Water-Environment Nexus in Deserts - Proceeding of the 1st International Conference on Sustainable Energy-Water-Environment Nexus in Desert Climates
Editors	Essam Heggy, Veronica Bermudez, Marc Vermeersch
Publisher	Springer Nature
Pages	649-656
Number of pages	8
ISBN (Print)	9783030760809
DOIs	https://doi.org/10.1007/978-3-030-76081-6_82
Publication status	Published - 2022
Externally published	Yes
Event	1st International Conference on Sustainable Energy-Water-Environment Nexus in Desert Climates, ICSEWEN 2019 - Ar-Rayyan, Qatar Duration: 2 Dec 2019 → 5 Dec 2019

Publication series

Name	Advances in Science, Technology and Innovation
ISSN (Print)	2522-8714
ISSN (Electronic)	2522-8722

Conference

Conference	1st International Conference on Sustainable Energy-Water-Environment Nexus in Desert Climates, ICSEWEN 2019
Country/Territory	Qatar
City	Ar-Rayyan
Period	2/12/19 → 5/12/19

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

SDG 7 Affordable and Clean Energy

Keywords

Au nanorods
Pesticide
Surface-enhanced Raman scattering (SERS)
TEMPO-oxidized nanocellulose fiber

Access to Document

10.1007/978-3-030-76081-6_82

Cite this

Abdul Hakkeem, H. M., Babu, A., & Pillai, S. (2022). High-Performance Au Nanorods as SERS Substrates for Environmental Monitoring Facilitated by the Organizing Power of Nanocellulose from Agave Palm Leaves, a Bio-Waste. In E. Heggy, V. Bermudez, & M. Vermeersch (Eds.), Sustainable Energy-Water-Environment Nexus in Deserts - Proceeding of the 1st International Conference on Sustainable Energy-Water-Environment Nexus in Desert Climates (pp. 649-656). (Advances in Science, Technology and Innovation). Springer Nature. https://doi.org/10.1007/978-3-030-76081-6_82

Abdul Hakkeem, Hasna M. ; Babu, Aswathy ; Pillai, Saju. / High-Performance Au Nanorods as SERS Substrates for Environmental Monitoring Facilitated by the Organizing Power of Nanocellulose from Agave Palm Leaves, a Bio-Waste. Sustainable Energy-Water-Environment Nexus in Deserts - Proceeding of the 1st International Conference on Sustainable Energy-Water-Environment Nexus in Desert Climates. editor / Essam Heggy ; Veronica Bermudez ; Marc Vermeersch. Springer Nature, 2022. pp. 649-656 (Advances in Science, Technology and Innovation).

@inproceedings{3759598f9e1844b097ad9fcee8d063f5,

title = "High-Performance Au Nanorods as SERS Substrates for Environmental Monitoring Facilitated by the Organizing Power of Nanocellulose from Agave Palm Leaves, a Bio-Waste",

abstract = "In search of a biocompatible and sustainable platform for surface-enhanced Raman scattering (SERS) studies, nanorods with a high aspect ratio of coinage metals such as gold, silver, and copper augment the peak intensity, but the shelf life of metal nanoparticles is questionable. Here, we report the synthetic strategy of parallelly aligned nanorods achieved by the synergetic action of carboxyl-functionalized nanocellulose fibers (TNCF) and cetyl trimethyl ammonium bromide (CTAB) as both reducing and capping agents. The synthesized parallel nanorods shows excellent SERS enhancement down to 10−7 M concentration of methylene blue and 0.1 ppm of thiram (pesticide). Additionally, TEMPO-oxidized nanocellulose fibers-supported nanorods colloid showed excellent shelf life. Our approach using TEMPO-oxidized nanocellulose fibers-supported Au nanorods can be considered an efficient and reproducible surface-enhanced Raman scattering substrate environmental monitoring.",

keywords = "Au nanorods, Pesticide, Surface-enhanced Raman scattering (SERS), TEMPO-oxidized nanocellulose fiber",

author = "\{Abdul Hakkeem\}, \{Hasna M.\} and Aswathy Babu and Saju Pillai",

note = "Publisher Copyright: {\textcopyright} 2022, The Author(s), under exclusive license to Springer Nature Switzerland AG.; 1st International Conference on Sustainable Energy-Water-Environment Nexus in Desert Climates, ICSEWEN 2019 ; Conference date: 02-12-2019 Through 05-12-2019",

year = "2022",

doi = "10.1007/978-3-030-76081-6\_82",

language = "English",

isbn = "9783030760809",

series = "Advances in Science, Technology and Innovation",

publisher = "Springer Nature",

pages = "649--656",

editor = "Essam Heggy and Veronica Bermudez and Marc Vermeersch",

booktitle = "Sustainable Energy-Water-Environment Nexus in Deserts - Proceeding of the 1st International Conference on Sustainable Energy-Water-Environment Nexus in Desert Climates",

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Abdul Hakkeem, HM, Babu, A & Pillai, S 2022, High-Performance Au Nanorods as SERS Substrates for Environmental Monitoring Facilitated by the Organizing Power of Nanocellulose from Agave Palm Leaves, a Bio-Waste. in E Heggy, V Bermudez & M Vermeersch (eds), Sustainable Energy-Water-Environment Nexus in Deserts - Proceeding of the 1st International Conference on Sustainable Energy-Water-Environment Nexus in Desert Climates. Advances in Science, Technology and Innovation, Springer Nature, pp. 649-656, 1st International Conference on Sustainable Energy-Water-Environment Nexus in Desert Climates, ICSEWEN 2019, Ar-Rayyan, Qatar, 2/12/19. https://doi.org/10.1007/978-3-030-76081-6_82

High-Performance Au Nanorods as SERS Substrates for Environmental Monitoring Facilitated by the Organizing Power of Nanocellulose from Agave Palm Leaves, a Bio-Waste. / Abdul Hakkeem, Hasna M.; Babu, Aswathy; Pillai, Saju.
Sustainable Energy-Water-Environment Nexus in Deserts - Proceeding of the 1st International Conference on Sustainable Energy-Water-Environment Nexus in Desert Climates. ed. / Essam Heggy; Veronica Bermudez; Marc Vermeersch. Springer Nature, 2022. p. 649-656 (Advances in Science, Technology and Innovation).

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution › peer-review

TY - GEN

T1 - High-Performance Au Nanorods as SERS Substrates for Environmental Monitoring Facilitated by the Organizing Power of Nanocellulose from Agave Palm Leaves, a Bio-Waste

AU - Abdul Hakkeem, Hasna M.

AU - Babu, Aswathy

AU - Pillai, Saju

PY - 2022

Y1 - 2022

N2 - In search of a biocompatible and sustainable platform for surface-enhanced Raman scattering (SERS) studies, nanorods with a high aspect ratio of coinage metals such as gold, silver, and copper augment the peak intensity, but the shelf life of metal nanoparticles is questionable. Here, we report the synthetic strategy of parallelly aligned nanorods achieved by the synergetic action of carboxyl-functionalized nanocellulose fibers (TNCF) and cetyl trimethyl ammonium bromide (CTAB) as both reducing and capping agents. The synthesized parallel nanorods shows excellent SERS enhancement down to 10−7 M concentration of methylene blue and 0.1 ppm of thiram (pesticide). Additionally, TEMPO-oxidized nanocellulose fibers-supported nanorods colloid showed excellent shelf life. Our approach using TEMPO-oxidized nanocellulose fibers-supported Au nanorods can be considered an efficient and reproducible surface-enhanced Raman scattering substrate environmental monitoring.

AB - In search of a biocompatible and sustainable platform for surface-enhanced Raman scattering (SERS) studies, nanorods with a high aspect ratio of coinage metals such as gold, silver, and copper augment the peak intensity, but the shelf life of metal nanoparticles is questionable. Here, we report the synthetic strategy of parallelly aligned nanorods achieved by the synergetic action of carboxyl-functionalized nanocellulose fibers (TNCF) and cetyl trimethyl ammonium bromide (CTAB) as both reducing and capping agents. The synthesized parallel nanorods shows excellent SERS enhancement down to 10−7 M concentration of methylene blue and 0.1 ppm of thiram (pesticide). Additionally, TEMPO-oxidized nanocellulose fibers-supported nanorods colloid showed excellent shelf life. Our approach using TEMPO-oxidized nanocellulose fibers-supported Au nanorods can be considered an efficient and reproducible surface-enhanced Raman scattering substrate environmental monitoring.

KW - Au nanorods

KW - Pesticide

KW - Surface-enhanced Raman scattering (SERS)

KW - TEMPO-oxidized nanocellulose fiber

UR - https://www.scopus.com/pages/publications/85129792477

U2 - 10.1007/978-3-030-76081-6_82

DO - 10.1007/978-3-030-76081-6_82

M3 - Conference contribution

AN - SCOPUS:85129792477

SN - 9783030760809

T3 - Advances in Science, Technology and Innovation

SP - 649

EP - 656

BT - Sustainable Energy-Water-Environment Nexus in Deserts - Proceeding of the 1st International Conference on Sustainable Energy-Water-Environment Nexus in Desert Climates

A2 - Heggy, Essam

A2 - Bermudez, Veronica

A2 - Vermeersch, Marc

PB - Springer Nature

T2 - 1st International Conference on Sustainable Energy-Water-Environment Nexus in Desert Climates, ICSEWEN 2019

Y2 - 2 December 2019 through 5 December 2019

ER -

Abdul Hakkeem HM, Babu A, Pillai S. High-Performance Au Nanorods as SERS Substrates for Environmental Monitoring Facilitated by the Organizing Power of Nanocellulose from Agave Palm Leaves, a Bio-Waste. In Heggy E, Bermudez V, Vermeersch M, editors, Sustainable Energy-Water-Environment Nexus in Deserts - Proceeding of the 1st International Conference on Sustainable Energy-Water-Environment Nexus in Desert Climates. Springer Nature. 2022. p. 649-656. (Advances in Science, Technology and Innovation). doi: 10.1007/978-3-030-76081-6_82

High-Performance Au Nanorods as SERS Substrates for Environmental Monitoring Facilitated by the Organizing Power of Nanocellulose from Agave Palm Leaves, a Bio-Waste

Abstract

Publication series

Conference

UN SDGs

Keywords

Access to Document

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