TY - JOUR
T1 - Plastic Fuel Conversion and Characterisation
T2 - A Waste Valorization Potential for Ghana
AU - Commeh, Michael
AU - Dodoo-Arhin, David
AU - Acquaye, Edward
AU - Baah, Isaiah Nimako
AU - Amoatey, Nene Kwabla
AU - Ephraim, James Hawkins
AU - Obada, David O.
AU - Minh, D. Pham
AU - Nzihou, A.
N1 - Publisher Copyright:
Copyright © Materials Research Society 2020.
PY - 2020
Y1 - 2020
N2 - Plastics generally play a very important role in a plethora of industries, fields and our everyday lives. In spite of their cheapness, availability and important contributions to lives, they however, pose a serious threat to the environment due to their mostly non-biodegradable nature. Recycling into useful products can reduce the amount of plastic waste. Thermal degradation (Pyrolysis) of plastics is becoming an increasingly important recycling method for the conversion of plastic materials into valuable chemicals and oil products. In this work, waste Polyethylene terephthalate (PET) water bottles were thermally converted into useful gaseous and liquid products. A simple pyrolysis reactor system has been used for the conversions with the liquid product yield of 65 % at a temperature range of 400°C to 550°C. The chemical analysis of the pyrolytic oil showed the presence of functional groups such as alkanes, alkenes, alcohols, ethers, carboxylic acids, esters, and phenyl ring substitution bands. The main constituents were 1-Tetradecene, 1-Pentadecene, Cetene, Hexadecane, 1-Heptadecene, Heptadecane, Octadecane, Nonadecane, Eicosane, Tetratetracontane, 1-Undecene, 1-Decene). The results are promising and can be maximized by additional techniques such as hydrogenation and hydrodeoxygenation to obtain value-added products.
AB - Plastics generally play a very important role in a plethora of industries, fields and our everyday lives. In spite of their cheapness, availability and important contributions to lives, they however, pose a serious threat to the environment due to their mostly non-biodegradable nature. Recycling into useful products can reduce the amount of plastic waste. Thermal degradation (Pyrolysis) of plastics is becoming an increasingly important recycling method for the conversion of plastic materials into valuable chemicals and oil products. In this work, waste Polyethylene terephthalate (PET) water bottles were thermally converted into useful gaseous and liquid products. A simple pyrolysis reactor system has been used for the conversions with the liquid product yield of 65 % at a temperature range of 400°C to 550°C. The chemical analysis of the pyrolytic oil showed the presence of functional groups such as alkanes, alkenes, alcohols, ethers, carboxylic acids, esters, and phenyl ring substitution bands. The main constituents were 1-Tetradecene, 1-Pentadecene, Cetene, Hexadecane, 1-Heptadecene, Heptadecane, Octadecane, Nonadecane, Eicosane, Tetratetracontane, 1-Undecene, 1-Decene). The results are promising and can be maximized by additional techniques such as hydrogenation and hydrodeoxygenation to obtain value-added products.
KW - mass spectroscopy
KW - polymer
KW - pyrolysis
KW - recycling
KW - waste management
UR - http://www.scopus.com/inward/record.url?scp=85097886708&partnerID=8YFLogxK
U2 - 10.1557/adv.2020.127
DO - 10.1557/adv.2020.127
M3 - Article
AN - SCOPUS:85097886708
SN - 2059-8521
VL - 5
SP - 1349
EP - 1356
JO - MRS Advances
JF - MRS Advances
IS - 26
ER -