Starch‐Polyvinyl Alcohol‐Based Films Reinforced with Chitosan Nanoparticles: Physical, Mechanical, Structural, Thermal and Antimicrobial Properties

The main purpose of the current study was to propose innovative composite films based on a corn starch/polyvinyl alcohol (PVA) blend (starch:PVA 40:60) and loaded with 3 different levels of chitosan nanoparticles (CNPs) (1, 3, and 5% w/v) to strengthen its physical, mechanical, structural, thermal and antimicrobial attributes. The synthesized CNPs were spherical with a particle size of ca. 100 nm as demonstrated by scanning electron microscopy (SEM) micrographs and dynamic light scattering tests. The results showed that the CNPs incorporation within the starch‐PVA 40:60 films promoted a uniform surface without any considerable pores. These films were characterized by a homogeneous CNP distribution within the polymer matrix, causing a significant decrease in water vapor permeability (WVP) (e.g., from 0.41 for the control film to 0.28 g.mm/kPa.h∙m² for the composite film loaded with 5% CNPs). The film solubility, transparency, glass transition and melting temperatures, and elongation at break were also reduced by increasing the CNP content from 1% to 5%, while total color and tensile strength parameters increased. The antibacterial effects of CNPs were more effective against Gram‐positive bacteria (Staphylococcus aureus) than Gramnegative bacteria (Escherichia coli and Salmonella typhimurium). It can be concluded that the addition of CNPs to the starch‐PVA matrix could improve its functional and technological attributes for food packaging applications.