Synthesis, structure, and ambident alkylation reactions of 3-aryl-1-(tetrazol-5′-yl)triazenes

Richard N. Butler; Declan P. Shelly; Victor C. Garvin

doi:10.1039/p19840001589

Synthesis, structure, and ambident alkylation reactions of 3-aryl-1-(tetrazol-5′-yl)triazenes

Richard N. Butler, Declan P. Shelly, Victor C. Garvin

National University of Ireland

Research output: Contribution to journal › Article › peer-review

12 Citations (Scopus)

Abstract

A series of 3-aryl-1-(tetrazol-5′-yl)triazenes was prepared by coupling tetrazole-5-diazonium ion with substituted anilines. The orientation of the ambident methylation reactions of the anion of these systems was investigated. ¹³C N.m.r. spectra of the mono- and di-methyl derivatives provided information on the preferred tautomeric structure of the parent triazenyltetrazole system.

Original language	English
Pages (from-to)	1589-1592
Number of pages	4
Journal	Journal of the Chemical Society, Perkin Transactions 1
DOIs	https://doi.org/10.1039/p19840001589
Publication status	Published - 1984
Externally published	Yes

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title = "Synthesis, structure, and ambident alkylation reactions of 3-aryl-1-(tetrazol-5′-yl)triazenes",

abstract = "A series of 3-aryl-1-(tetrazol-5′-yl)triazenes was prepared by coupling tetrazole-5-diazonium ion with substituted anilines. The orientation of the ambident methylation reactions of the anion of these systems was investigated. 13C N.m.r. spectra of the mono- and di-methyl derivatives provided information on the preferred tautomeric structure of the parent triazenyltetrazole system.",

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year = "1984",

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journal = "Journal of the Chemical Society, Perkin Transactions 1",

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T1 - Synthesis, structure, and ambident alkylation reactions of 3-aryl-1-(tetrazol-5′-yl)triazenes

AU - Butler, Richard N.

AU - Shelly, Declan P.

AU - Garvin, Victor C.

PY - 1984

Y1 - 1984

N2 - A series of 3-aryl-1-(tetrazol-5′-yl)triazenes was prepared by coupling tetrazole-5-diazonium ion with substituted anilines. The orientation of the ambident methylation reactions of the anion of these systems was investigated. 13C N.m.r. spectra of the mono- and di-methyl derivatives provided information on the preferred tautomeric structure of the parent triazenyltetrazole system.

AB - A series of 3-aryl-1-(tetrazol-5′-yl)triazenes was prepared by coupling tetrazole-5-diazonium ion with substituted anilines. The orientation of the ambident methylation reactions of the anion of these systems was investigated. 13C N.m.r. spectra of the mono- and di-methyl derivatives provided information on the preferred tautomeric structure of the parent triazenyltetrazole system.

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U2 - 10.1039/p19840001589

DO - 10.1039/p19840001589

M3 - Article

AN - SCOPUS:37049109832

SN - 1472-7781

SP - 1589

EP - 1592

JO - Journal of the Chemical Society, Perkin Transactions 1

JF - Journal of the Chemical Society, Perkin Transactions 1

ER -

Synthesis, structure, and ambident alkylation reactions of 3-aryl-1-(tetrazol-5′-yl)triazenes

Abstract

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